聚醚醚酮、聚砜及聚酯的复合材料在模拟生理环境中的力学性能研究
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上海市医学领先专业重点学科基金(1995-Ⅳ-008)


A STUDY ON MECHANICAL PROPERTIES OF THE COMPOSITES OF POLYTHERETHERETONE, POLYSULPHONE AND POLYESTER IN IMITATIVE PHYSIOLOGICAL ENVIRONMENT
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    摘要:

    目的:研究碳纤维增强的聚醋、聚砜和聚醚醚酮复合材料在生理环境中的力学性能降解特性。方法:将试样分别浸泡于37℃、65℃和95℃生理盐水中,并在0~256天的时间段内分别测量材料的抗压强度和弹性模量,干燥试样作为对照。计算材料强度和模量降解的百分比。结果:在给定时间和温度的条件下,CFR/PEEK在生理盐水环境中的抗压强度和弹性模量均无明显改变。而CFR/PE和CFR/PSF则随浸泡时间的延长,抗压强度和弹性模量明显降低。其降低值与时间和温度均相关。结论:CFR/PEEK在生理环境中具有良好的生物力学稳定性,而CFR/PE和CFR/PSF在应用于体内时则必须考虑材料的力学降解特性。

    Abstract:

    Objective: To study the mechanical degradation characteristic of carbon fiber reinforced polyester(CFR/PE), polysulfone (CFR/PSF) and polyetheretherketone (CFR/PEEK) in. physiologicalenvironment. Methods : Compressive strength and modulus of three samples were tested fbllowingconditioning in physiological saline at 37℃, 65℃ and 95℃ for time periods from 0 to 256 days. Drysamples were used as controls. The percentage value of degradation of compressive strength andmodulus of each of the materials were calculated and compared. Results :No significant loss incompressive strength and modulus values of CFR/PEEK of the saline-saturated or dry controlsamples as a function of conditioning time or temperature. However, the compressive strength andmodulus of CFR/PE and CFR/PSF were significantly decreased as long as saline saturate. Thecompressive property value of CFR/PE and CFR/PSF are corelative to both time and temperature.Conclusionf There is satisfactory biomechanical stability of CFR/PEEK in physiologicalenvironment. It must be taken into consideration of materials' mechanical degradation propertieswhen CFR/PE and CFR/PSF be used in vivo as implants.

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石志才,侯铁胜,李家顺,贾连顺,戈俊国.聚醚醚酮、聚砜及聚酯的复合材料在模拟生理环境中的力学性能研究[J].医用生物力学,1998,13(4):193-199

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